Omethanesulfonate ([OTf-]), fluoroalkyl (m = 3, 7, 9) and alkyl chains (n = ten, 12, 14) as well as diverse counterions bis(trifluoromethane)sulfonimide ([Tf2N-]), and tetrafluoroborate ([BF4-]). This loved ones is for example trifluoromethanesulfonate ([OTf- ]), bis(trifluoromethane)sulfonimide ([Tf2 N- ]), proposed as thermotropic triphilic ionic liquid crystals, displaying predominantly smectic and tetrafluoroborate ([BF4 – ]). This household is proposed as thermotropic triphilic ionic A (SmA) phases, which can be dominantly attributed towards the ionic PX-478 In Vitro nature of those components liquid crystals, displaying predominantly smectic A (SmA) phases, which is often dominantly also as for the alkyl and perfluoroalkyl chains [10,147]. Compared to this family members, the attributed for the ionic nature of those supplies as well as to the alkyl and perfluoroalkyl perfluoroheptyl 1,2,4-oxadiazoles bearing a N-methylated-4-pyridyl moiety (visualized in chains [10,147]. In comparison to this family members, the perfluoroheptyl 1,2,4-oxadiazoles bearing Chart 1) with iodide [I-] or [OTf-] as counterions behave as ionic liquids, as a result, being lowa N-methylated-4-pyridyl moiety (visualized in Chart 1) with iodide [I- ] or [OTf- ] as melting organic salts. Even so, the N-methylated-3-pyridyl moiety has been located to counterions behave as ionic liquids, as a result, being low-melting organic salts. Nevertheless, the exhibit thermally induced liquid crystalline behavior [10]. To be able to drive N-methylated-3-pyridyl moiety has been found to exhibit thermally induced liquid crys1,two,4-oxadiazoles together with the 4-substituted pyridinium to LC formation, the mixture of talline behavior [10]. As a way to drive 1,2,4-oxadiazoles with the 4-substituted pyridinium perfluoroheptyl chains and thethe mixture of perfluoroheptyl into the systemintroduction of long to LC formation, introduction of lengthy alkyl chains chains along with the are a promising way to acquire micro-segregation resulting in ionic liquid crystalline behavior. resulting in alkyl chains into the technique are a promising approach to receive micro-segregation As a result, we focused liquid crystalline behavior. Therefore, we focused on newsynthesis and characterization ionic around the synthesis and characterization of a the class of 1,2,4oxadiazolylpyridinium salts as cationic scaffold for fluorinated ionic liquid crystals. The fluorinated of a new class of 1,2,4-oxadiazolylpyridinium salts as cationic scaffold for 12 salts of this ionic liquid crystals. TheChart 1 and this perform are summarized in Chart 1 and differ in work are summarized in 12 salts of differ in the reciprocal Fmoc-Gly-Gly-OH Autophagy position from the perfluoroheptyl chain as well as the pyridinium moieties on the interspacing oxadiazole ring, the reciprocal position of your perfluoroheptyl chain and also the pyridinium moieties around the resulting in 1a-f and 2a-f getting regioisomers.resulting in 1a-f andchains of diverse length Additionally, interspacing oxadiazole ring, Furthermore, alkyl 2a-f becoming regioisomers. (C10H21 for 1a,d and chains ofH25 for 1b,e and 2b,e;H21 H29 for 1c,f and 2c,f)12 H25 for 1b,e and 2b,e; C14 H29 alkyl 2a,d; C12 distinctive length (C10 C14 for 1a,d and 2a,d; C are inserted into – the program. Also, 2c,f) are inserted into[Br-] system. Additionally, iodide [I- ], bromide [Br- ] or for 1c,f and iodide [I ], bromide the or bis(trifluoromethane)sulfonimide -] are viewed as as counterions. The synthesis, – [Tf2N bis(trifluoromethane)sulfonimide [Tf2 N metathesis, structure, and liquidThe synthesis, ] are viewed as as counte.
